Catalysts for polyethylene production and use thereof

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Organic compound containing

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502152, 502153, 502171, 502232, 502305, 502308, 502309, 502319, 502320, B01J 2104, B01J 2108, B01J 2326, B01J 3134

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060966793

ABSTRACT:
A process for producing a chromium-based catalyst for the production of polyethylene, the process comprising the steps of providing a catalyst support selected from silica, silica-titania and silica-zirconia; reacting the support with one of an aluminium alkyl compound or a chromium salt compound selected from at least one of chromium (III) acetylacetonate, chromium (III) acetate, chromium (III) oxalate and chromium (III) stearate; and thereafter reacting the support with the other of the aluminium alkyl compound or the chromium salt to produce a chromium-impregnated catalyst having a silica-alumina support, the catalyst composition comprising from 0.4 to 1.5 wt % chromium, based on the weight of the chromium-based catalyst and the alumina in the silica-containing support comprising from 0.5 to 4 wt % aluminium in the chromium-based catalyst.

REFERENCES:
patent: 3755197 (1973-08-01), Hsieh
patent: 5079317 (1992-01-01), Tajima et al.
patent: 5723399 (1998-03-01), Takemoto et al.

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