Catalysts for para-ethyltoluene dehydrogenation

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Inorganic carbon containing

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502243, 502311, 502330, 585444, 585445, B01J 2378, B01J 2384, B01J 2386

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active

045045941

ABSTRACT:
Para-ethyltoluene dehydrogenation catalyst compositions and processes for using such catalysts are provided. The catalyst compositions comprise a catalytically active iron compound, e.g., iron oxide; a potassium catalyst promoter, e.g., potassium carbonate; an optional chromium compound stabilizer, e.g., chromic oxide, and a bismuth compound, e.g., bismuth trioxide. Utilization of particular amounts of bismuth compound in dehydrogenation catalyst compositions of this type will provide a catalyst especially suitable for promoting the selective dehydrogenation of para-ethyltoluene to form para-methylstyrene in improved yields.

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