Catalysts for oxygen-initiated free-radical polymerization react

Details Catalysts for oxygen-initiated free-radical polymerization react Catalysts for oxygen-initiated free-radical polymerization react

1981-08-07

1983-07-26

Konopka, P. E.

Compositions

Preservative agents

Anti-oxidants or chemical change inhibitants

252428, 525 17, 525245, C08L 6706, C08L 6700, C08F 432, B01J 3112

Patent

active

043953611

ABSTRACT:
A class of new oxygen-activated free-radical polymerization catalysts, comprising specifically-defined autoxidizable cyclic hydrocarbons together with cobalt(II) compounds, is disclosed. A method of catalyzing an oxygen-initiated free-radical polymerization reaction using these catalysts is also disclosed.

REFERENCES:
patent: 3190878 (1965-06-01), Ikeda
patent: 4242243 (1980-12-01), Antonelli et al.
patent: 4244850 (1981-01-01), Mylonakis
patent: 4261872 (1981-04-01), Emmons et al.
patent: 4309511 (1982-01-01), Jefferson et al.
Hochberg, J. Oil and Colour Chemists Assoc., 48, 1048-1068 (1965).
Akashi, Kogyo Kagaku Zasshi, 66, 156 (1963).
Prane, Polymer News, 4, 239-241 (1978).
Imoto, et al., J. Poly. Sci., 17, 385-392 (1979).

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