Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing
Reexamination Certificate
2005-07-08
2008-10-28
Harlan, Robert D. (Department: 1796)
Organic compounds -- part of the class 532-570 series
Organic compounds
Heavy metal containing
C502S155000, C502S167000, C526S171000, C526S172000
Reexamination Certificate
active
07442819
ABSTRACT:
Novel iron and cobalt complexes of certain novel tricyclic ligands containing a “pyridine” ring and substituted with two imino groups are polymerization and/or oligomerization catalysts for olefins, especially ethylene. Depending on the exact structure of the ligand, and polymerization process conditions, products ranging from α-olefins to high polymers may be produced. The polymers, especially polyethylenes, are useful for films and as molding resins.
REFERENCES:
patent: 3781291 (1973-12-01), Sulzbach
patent: 5866663 (1999-02-01), Brookhart et al.
patent: 5955555 (1999-09-01), Bennett et al.
patent: 6063881 (2000-05-01), Bennett et al.
patent: 6103946 (2000-08-01), Brookhart et al.
patent: 6184171 (2001-02-01), Shih et al.
patent: 6214761 (2001-04-01), Bennett et al.
patent: 6252002 (2001-06-01), Yamada et al.
patent: 6297338 (2001-10-01), Cotts et al.
patent: 6313061 (2001-11-01), Denton et al.
patent: 6399535 (2002-06-01), Shih et al.
patent: 6403521 (2002-06-01), Ishii et al.
patent: 6407188 (2002-06-01), Guan et al.
patent: 6451939 (2002-09-01), Britovsek et al.
patent: 6455660 (2002-09-01), Clutton et al.
patent: 6458739 (2002-10-01), Kimberley et al.
patent: 6472341 (2002-10-01), Kimberley et al.
patent: 6534691 (2003-03-01), Culver et al.
patent: 6545108 (2003-04-01), Moody et al.
patent: 6555631 (2003-04-01), Wang et al.
patent: 6555723 (2003-04-01), Schiffino et al.
patent: 6559091 (2003-05-01), Moody et al.
patent: 6579832 (2003-06-01), Jimenez et al.
patent: 6586541 (2003-07-01), Citron et al.
patent: 6610805 (2003-08-01), Guram et al.
patent: 6620895 (2003-09-01), Cotts et al.
patent: 6620897 (2003-09-01), Smillie et al.
patent: 6657026 (2003-12-01), Kimberley et al.
patent: 6683187 (2004-01-01), De Boer et al.
patent: 6710006 (2004-03-01), De Boer et al.
patent: WO 99/12981 (1999-03-01), None
patent: WO 99/46302 (1999-09-01), None
patent: WO 99/46303 (1999-09-01), None
patent: WO 99/46304 (1999-09-01), None
patent: WO 00/24788 (2000-05-01), None
patent: WO 00/32641 (2000-06-01), None
patent: WO 00/50470 (2000-08-01), None
patent: WO 00/69869 (2000-11-01), None
patent: WO 00/69923 (2000-11-01), None
patent: WO 00/73249 (2000-12-01), None
patent: WO 02/079276 (2002-10-01), None
patent: WO 02/083751 (2002-10-01), None
patent: WO 03/059511 (2003-07-01), None
patent: WO 2004/026795 (2004-04-01), None
Greon et al., Eur. J. Inorg. Chem. 1998, 1129-1143.
U.S. Appl. No. 60/505,906, filed Sep. 25, 2003, Spence et al.
Johannes H. Groen et al., Insertion Reactions Into Palladium-Carbon Bonds Of Complexes Containing Terdentate Nitrogen Ligands: Experimental And Ab Initio MO Studies, European Journal Of Inorganic Chemistry 1998, vol. 8, pp. 1129-1143.
Alison M. A. Bennett et al., Novel, Highly Active Iron and Cobalt Catalysts For Olefin Polymerization, Chemtech, 1999, vol. 29, pp. 24-28.
Wolfgang Beck et al., metal Complexes Of Weakly Coordinating Anions. Precursors of Strong Cationic Organometallic lewis Acids, American Chemical Society, 1988, vol. 88, pp. 1405-1421.
Steven H. Strauss et al., The Search For Larger And More Weakly Coordinating Anions, American Chemical Society, 1993, vol. 93, pp. 927-942.
Brooke L. Small et al.., Highly Active Iron And Cobalt Catalysts For The Polymerization Of Ethylene, American Chemical Society, 1998, vol. 120, pp. 4049-4050.
R.P. Thummel et al., Polyaza Cavilty Shaped Molecules. 4. Annelated Derivatives Of 2,2′:6′,2″—Terpyridine, 1985, vol. 50, pp. 2407-2412.
Ionkin Alex Sergey
Johnson Lynda Kaye
E. I. du Pont de Nemours and Company
Harlan Robert D.
LandOfFree
Catalysts for olefin polymerization or oligomerization does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Catalysts for olefin polymerization or oligomerization, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Catalysts for olefin polymerization or oligomerization will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-4018427