Catalysts for lean burn engine exhaust abatement

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Nitrogen or nitrogenous component

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C423S239200, C423S213200, C423S213500

Reexamination Certificate

active

06514470

ABSTRACT:

BACKGROUND OF THE INVENTION
Removal of NO
x
from exhaust streams is a critical technology for the automotive and electric power industry in meeting ever more stringent air emissions standards. In view of future emissions standards automotive companies have focused on the design of lean-burn engine designs where the combustion fuel to air ratio is substantially less than the stoichiometric ratio used in present day engines. Under lean burn conditions, the existing catalytic converter technology does not work. Thus, new catalytic converters must be developed for lean burn engine technology to be implemented. Lean burn deNO
x
catalysts are highly sought after and are the focus of considerable research worldwide. A rather narrow window of satisfactory operating temperatures has characterized most catalysts for lean burn applications. Specifically, they only effectively convert NO
x
over small temperature ranges that do not always match the temperatures at which the NO
x
is emitted. Some of the better catalyst materials have included metal-substituted zeolite catalysts such as Cu-ZSM-5 and related catalysts consisting of various zeolites with metal ions substituted into the zeolite structure. These materials offer activity at higher temperatures than conventional platinum-based deNO
x
catalysts, but the best operating temperature ranges are generally too high (above about 400° C.) and too narrow (only about 100° C. in effective range width).
In addition, internal combustion engines emit a large amount of unburned hydrocarbons during cold engine start-up. In fact, a rather large fraction of the total emitted hydrocarbons released during the first minutes of engine operation are due to the uncombusted hydrocarbons in the rich fuel mixture. Such release of hydrocarbons after engine start-up poses a special problem, as at that point the temperatures of the exhaust gas and the catalytic converter are generally not high enough for conversion of the gaseous pollutants by conventional catalysts. The catalysts in present catalytic converter systems are generally ineffective at ambient temperatures and must reach high temperatures, often in the range of 300° C. to 400° C. before they become effective.
For example, U.S. Pat. No. 5,171,553 describes the catalytic decomposition of N
2
O from gaseous mixtures, but conversion or decomposition rates of 50 percent of the N
2
O are shown as requiring temperatures of greater than about 275° C. as shown in their FIG. 3 for rhodium-exchanged zeolites and of greater than about 350° C. as shown in their FIGS. 1 and 2 for copper- and cobalt-exchanged zeolites.
U.S. Pat. No. 5,776,423 describes the catalytic decomposition of NO
x
gaseous mixtures, but shows conversion or decomposition rates of less than 50 percent of the NO
x
at temperatures of less than about 375° C. even before aging of the catalyst as shown in their FIG. 1.
Numerous other patents such as U.S. Pat. No. 5,935,529, U.S. Pat. No. 5,869,013, U.S. Pat. No. 5,834,395, U.S. Pat. No. 5,695,728, U.S. Pat. No. 5,449,504, U.S. Pat. No. 5,443,803, U.S. Pat. No. 5,427,753, U.S. Pat. No. 5,358,916, U.S. Pat. No. 5,260,043, and U.S. Pat. No. 5,171,553, either describe the problems of treating exhaust gases at temperatures below 300° C. to 400° C. or fail to show conversion rates of 50 percent or more at temperatures below about 300° C. to 400° C.
Catalysts have now been found which overcome these obstacles and provide for effective NO
x
conversion at lower temperatures and a wider temperature range.
It is an object of this invention to provide a process for NO
x
conversion in an exhaust stream under temperature conditions of from about 200° C. to about 600° C.
Another object of this invention is a process for NO
x
conversion of at least about 60 percent in an exhaust stream under temperature conditions of from about 200° C. to about 600° C., especially from about 200° C. to about 400° C.
Yet another object of the present invention is to provide for NO
x
conversion in an exhaust stream with a broad effective operating range, i.e., a high conversion rate such as at least about 60 percent for a temperature range of greater than 200° C., preferably greater than 300° C.
Still another object of the present invention is to provide compositions of matter useful for the catalytic reduction of nitrogen oxides in an exhaust stream under temperature conditions of from about 200° C. to about 600° C., especially from about 200° C. to about 400° C.
SUMMARY OF THE INVENTION
To achieve the foregoing and other objects, and in accordance with the purposes of the present invention, as embodied and broadly described herein, provides a process for catalytically reducing nitrogen oxides in an exhaust gas stream containing nitrogen oxides and a reductant material including contacting said gas stream under conditions effective to catalytically reduce said nitrogen oxides with a catalyst comprising a aluminum-silicate type material and a minor amount of a metal, said catalyst characterized as having sufficient catalytic activity so as to reduce the nitrogen oxides by at least 60 percent under temperatures within the range of from about 200° C. to about 400° C.
The present invention further provides a composition of matter, useful in a process for catalytically reducing nitrogen oxides in an exhaust gas stream containing nitrogen oxides and a reductant material, comprising a ferrierite material having undergone a pretreatment by contact with a dilute solution of a material selected from the group consisting of ammonium fluoride, ammonium nitrate, ammonium chloride, nitric acid, hydrochloric acid, hydrofluoric and oxalic acid for a sufficient period of time to allow for catalytically reducing nitrogen oxides in an exhaust gas stream containing nitrogen oxides and a reductant material by at least 60 percent under temperatures within the range of from about 200° C. to about 600° C. Such pretreatment is conducted for ferrierite material obtained from Tosoh Corporation whereas no pretreatment is conducted for ferrierite material obtained from Zeolyst Corp.


REFERENCES:
patent: 4016245 (1977-04-01), Plank et al.
patent: 4046685 (1977-09-01), Bray
patent: 5118483 (1992-06-01), Barri
patent: 5171553 (1992-12-01), Li et al.
patent: 5260043 (1993-11-01), Li et al.
patent: 5358916 (1994-10-01), Shiokawa et al.
patent: 5407651 (1995-04-01), Kawai
patent: 5427753 (1995-06-01), Miura et al.
patent: 5443803 (1995-06-01), Mizuno et al.
patent: 5433933 (1995-07-01), Eshita et al.
patent: 5449504 (1995-09-01), Kasahara et al.
patent: 5451385 (1995-09-01), Hansel et al.
patent: 5695728 (1997-12-01), Miura et al.
patent: 5776423 (1998-07-01), Feeley et al.
patent: 5807528 (1998-09-01), Nakano et al.
patent: 5834395 (1998-11-01), Honda
patent: 5869013 (1999-02-01), Tabata et al.
patent: 5935529 (1999-08-01), Saito et al.
patent: 5968462 (1999-10-01), Suzuki
patent: 5968463 (1999-10-01), Shelef et al.
patent: 5968466 (1999-10-01), Kharas
patent: 5985225 (1999-11-01), Ohtsuka et al.
patent: 5993764 (1999-11-01), Tabata et al.
patent: 6010673 (2000-01-01), Kanazawa et al.
patent: 6063351 (2000-05-01), Hamon et al.
patent: 6074976 (2000-06-01), Tabata et al.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Catalysts for lean burn engine exhaust abatement does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Catalysts for lean burn engine exhaust abatement, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Catalysts for lean burn engine exhaust abatement will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3121323

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.