Catalyst systems for improved stereoselectivity and broader mole

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...

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Details

502114, 502115, 502116, B01J10100, B01J10110, B01J10140, B01J10150

Patent

active

061470244

ABSTRACT:
The present invention provides a catalyst for the polymerization of olefin that exhibits improved selectivity and broader molecular weight distribution in the polymer product. The catalyst is a conventional supported Ziegler-Natta catalyst in combination with a mixture of at least two electron donors, both having the general formula SiR.sub.m (OR').sub.4-m where R is selected from the group consisting of an alkyl group, a cycloalkyl group, an aryl group and a vinyl group; R' is an alkyl group; and m is 0-3, wherein when R is an alkyl group, R may be identical with R'; when m is 0, 1 or 2, the R' groups may be identical or different; and when m is 1, 2 or 3, the R groups may be identical or different. This catalyst produces polypropylene having xylene solubles of 1-7 to 5.1 wt % and a molecular weight distribution of about 10.

REFERENCES:
patent: 5494872 (1996-02-01), Hosaka et al.

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