Catalyst systems for ethylene oligomerisation to linear...

Details Catalyst systems for ethylene oligomerisation to linear... Catalyst systems for ethylene oligomerisation to linear...

2006-05-30

2006-05-30

Harlan, Robert D. (Department: 1713)

Catalyst, solid sorbent, or support therefor: product or process

Catalyst or precursor therefor

Organic compound containing

C502S167000, C502S168000, C526S161000, C526S171000, C526S172000, C556S138000

Reexamination Certificate

active

07053020

ABSTRACT:
A catalyst system comprising:(a) one or more bisarylimino pyridine iron or cobalt catalysts;(b) a first co-catalyst compound which is selected from aluminium alkyls, aluminoxanes, and mixtures thereof; and(c) a second co-catalyst compound which comprises one or more compounds of the formula ZnR′2wherein each R′, which may be the same or different, is selected from hydrogen, optionally substituted C1–C20hydrocarbyl, phenyl, Cl, Br, I, SR″, NR″2, OH, OR″, CN, NC wherein R″, which within the same molecule may the same or different, is C1–C20hydrocarbyl.

REFERENCES:
patent: 4728583 (1988-03-01), Yamazaki et al.
patent: 4912333 (1990-03-01), Roberts et al.
patent: 4944026 (1990-07-01), Arakawa et al.
patent: 5151604 (1992-09-01), Kohda et al.
patent: 5318935 (1994-06-01), Canich et al.
patent: 5726115 (1998-03-01), Horton et al.
patent: 5830629 (1998-11-01), Vizard et al.
patent: 5852145 (1998-12-01), McLain et al.
patent: 5888647 (1999-03-01), Yamane
patent: 5905014 (1999-05-01), Van de Bergh
patent: 5955555 (1999-09-01), Bennett
patent: 6002034 (1999-12-01), McLain et al.
patent: 6063881 (2000-05-01), Bennett
patent: 6103946 (2000-08-01), Brookhart, III et al.
patent: 6150482 (2000-11-01), Brookhart et al.
patent: 6214761 (2001-04-01), Bennett
patent: 6232259 (2001-05-01), Ittel et al.
patent: 6265500 (2001-07-01), Debras
patent: 6310153 (2001-10-01), Ittel et al.
patent: 6395668 (2002-05-01), van Baar et al.
patent: 6407188 (2002-06-01), Guan et al.
patent: 6414098 (2002-07-01), Engehausen et al.
patent: 6417364 (2002-07-01), Lenges
patent: 6423848 (2002-07-01), Bennett
patent: 6432862 (2002-08-01), Bennett
patent: 6441117 (2002-08-01), Cameron
patent: 6451939 (2002-09-01), Britovsek et al.
patent: 6455660 (2002-09-01), Clutton et al.
patent: 6458739 (2002-10-01), Kimberley et al.
patent: 6458905 (2002-10-01), Schmidt et al.
patent: 6461994 (2002-10-01), Gibson et al.
patent: 6462152 (2002-10-01), Berardi et al.
patent: 6462155 (2002-10-01), Okuda
patent: 6465386 (2002-10-01), Maddox et al.
patent: 6472341 (2002-10-01), Kimberley et al.
patent: 6479601 (2002-11-01), Kerns et al.
patent: 6489497 (2002-12-01), Brookhart, III et al.
patent: 6521329 (2003-02-01), Aylward et al.
patent: 6534691 (2003-03-01), Culver et al.
patent: 6545108 (2003-04-01), Moody et al.
patent: 6548672 (2003-04-01), Gibson et al.
patent: 6555723 (2003-04-01), Schiffino
patent: 6559091 (2003-05-01), Moody et al.
patent: 6559252 (2003-05-01), Horton et al.
patent: 6583237 (2003-06-01), Imuta et al.
patent: 6605677 (2003-08-01), Lavoie et al.
patent: 6677267 (2004-01-01), Berardi et al.
patent: 6683141 (2004-01-01), Gibson et al.
patent: 6683187 (2004-01-01), De Boer et al.
patent: 6706891 (2004-03-01), Ponasik
patent: 6710006 (2004-03-01), De Boer et al.
patent: 6740715 (2004-05-01), Brookhart, III et al.
patent: 6825297 (2004-11-01), Devore et al.
patent: 6838540 (2005-01-01), Mitani et al.
patent: 2001/0000519 (2001-04-01), Bennett
patent: 2001/0016634 (2001-08-01), lttel et al.
patent: 2002/0013431 (2002-01-01), Bennett
patent: 2002/0016425 (2002-02-01), De Boer et al.
patent: 2002/0016521 (2002-02-01), Culver et al.
patent: 2002/0019575 (2002-02-01), Schiffino
patent: 2002/0028941 (2002-03-01), De Boer et al.
patent: 2002/0035031 (2002-03-01), Berardi et al.
patent: 2002/0128409 (2002-09-01), De Boer et al.
patent: 2003/0036615 (2003-02-01), Brookhart, III et al.
patent: 2003/0045752 (2003-03-01), De Boer et al.
patent: 2003/0050494 (2003-03-01), Brookhart, III et al.
patent: 2003/0119921 (2003-06-01), De Boer et al.
patent: 2003/0125195 (2003-07-01), Britovsek et al.
patent: 2003/0144514 (2003-07-01), De Boer et al.
patent: 2003/0195110 (2003-10-01), Moody et al.
patent: 2003/0225228 (2003-12-01), Moody et al.
patent: 2004/0116758 (2004-06-01), De Boer et al.
patent: 2005/0014983 (2005-01-01), De Boer et al.
patent: 0 308 728 (1989-03-01), None
patent: 1125928 (2001-08-01), None
patent: 1125987 (2001-08-01), None
patent: 1127987 (2001-08-01), None
patent: 0 927 201 (2004-04-01), None
patent: 04325504 (1992-11-01), None
patent: 418462 (1974-09-01), None
patent: WO 92/12162 (1992-07-01), None
patent: WO 96/27439 (1996-09-01), None
patent: WO 98/27124 (1998-06-01), None
patent: WO 99/02472 (1999-01-01), None
patent: WO 99/12981 (1999-03-01), None
patent: WO 99/50273 (1999-10-01), None
patent: WO 99/51550 (1999-10-01), None
patent: 99/62967 (1999-12-01), None
patent: WO 00/08034 (2000-02-01), None
patent: WO 00/15646 (2000-03-01), None
patent: WO 00/20427 (2000-04-01), None
patent: WO 00/24788 (2000-05-01), None
patent: WO 00/50470 (2000-08-01), None
patent: WO 01/36379 (2001-05-01), None
patent: WO 01/58874 (2001-08-01), None
patent: WO 02/00339 (2002-01-01), None
patent: WO 02/06192 (2002-01-01), None
patent: WO 02/12151 (2002-02-01), None
patent: WO 02/28805 (2002-04-01), None
patent: WO 03/000628 (2003-01-01), None
patent: WO 03/011876 (2003-02-01), None
U.S. Appl. No. 09/964,714, filed Sep. 27, 2001, De Boer et al.
U.S. Appl. No. 10/208,535, filed Jul. 30, 2002, De Boer et al.
U.S. Appl. No. 10/739,715, filed Dec. 18, 2003, De Boer et al.
U.S. Appl. No. 10/320,213, filed Dec. 16, 2002, De Boer et al.
D. van Leusen and B. Hesen, Organometallics, 2001, 20, pp. 224-226.
Chemical Abstracts, vol. 134, Columbus, Ohio, US; Abstract No. 231149, Radecka-Paryzek, W. et al., “Metal-Ion-Dispersed Synthesis of Homo- and Heteronuclear Dimetallic Schiff Base Podates,” Pol. J. Chem. 2001, 75(1), pp. 35-42.
D. Vogt, Oligomerisation of ethylene to higher alpha-olefins in Applied Homogeneous Catalysis with organometallic Compounds, Ed. B. Comils, W. A. Herrmann, 2nd lEdition, vol. 1, Ch. 2.3.1.1, p. 240-253, Wiley-VCH 2002).
Angew. Chem. Int. ED. 2002, 41, No. 3, “Iron-Catalyzed Polyethylene Chain Growth on Zinc: Linear α-Olefins With a Poisson Distribution,” by George J. P. Britovsek, et al., pp. 489-491.
“Late Metal Catalysts for Ethylene Homo- and Copolymerization,” by Steven D. Ittel et al., Chemical Reviews, American Chemical Society, Easton, US, vol. 100, No. 4, 2000, pp. 1169-1203.
Oligomerisation of Ethylene by Bis(imino)pydidyliron and -cobalt Complexes, by George J. P. Britovsek et al., Chemistry—A European Journal, VCH Publishers, US, vol. 6, No. 12, 2000, pp. 2221-2231.
“Novel Olefin Polymerization Catalysts Based on Iron and Cobalt,” by George J. P. Britovsek et al., Chemical Communications-Chemcom, Roayl Society of Chemistry, GB, No. 7, 1998, pp. 849-850.
“Olefin Polymerization with [{bis(imino)pyridyl}CO” Cl2]: Generation of the Active Species Involves CO1** , by Martijn Kooistra et al., Angewandte Chemie. International Edition, WILEY-VCH, Weinheim, DE, vol. 40, No. 24, Dec. 17, 2001, pp. 4719-4722.
“The Nature of the Active Species in Bis(imino)pyridyl Cobalt Ethylene Polymerisation Catalysts,” by Vernon C. Gibson, et al., Chemical Communications-Chemcom, Royal Society of Chemistry, GB. No. 21, 2001, pp. 2252-2253.
“Iron-Based Catalysts with Exceptionally High Activities and Selectivities for Oligomerization of Ethylene to Linear α-Olefins,” by Brooke L. Small et al., Journal of the American Chemical Society, Washington, DC, vol. 120, No. 28, Jul. 22, 1998, pp. 7143-7144.
Paul E. Figgins et al., “Complexes of Iron (II), Corbalt (II) and Nickel (II) with Biacetyl-bis-methylimine, 2-Pyridinal-methylimine and 2,6-Pyridindial-bis-methylimine,” J. Am. Chem. Soc. (1960) vol. 82, pp. 820-824.
Francis Lions et al., “Tridentate Chelate Compounds. I,” J. Am Chem. Soc. (1957), vol. 79, pp. 2733-2738.
“Novel, Highly Active Iron and Cobalt Catalysts for Olefin Polymerization,” by Allsion M. A. Bennett,ChemtechJul. 1999, pp. 24-28.
“Polymerization of Propylene by a New Generation of Iron Catalysts: Mechanisms of Chain Initiation, Propagation, and Termination,” by Brooke L. Small and Maurice Brookhart, Macromolecules, vol. 32, No. 7, 1999, pp. 21210-2130.
“Metal-Ion-Directed Sythesis of

Affiliated with

Also associated with

Rating

Catalyst systems for ethylene oligomerisation to linear... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Catalyst systems for ethylene oligomerisation to linear..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Catalyst systems for ethylene oligomerisation to linear... will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-3568217