Catalyst system, process, and silicone compositions

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From silicon reactant having at least one...

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528 32, 528 33, 528 34, 528 39, 528 38, 528 21, 556457, 522 99, 502158, 502167, C08G 7708

Patent

active

061404446

ABSTRACT:
The invention relates to a catalyst system for reacting a silanol group with an alkoxysilane containing a polymerizable ethylenically unsaturated group. The catalyst system includes an organo-lithium reagent and a hydroxylamine. The catalyst system, permits reaction of the silanol group with alkoxysilanes containing rapidly polymerizable ethylenically unsaturated groups, such as an acryloxyalkyl group, for instance an acryloxypropyl group.

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patent: 4798889 (1989-01-01), Plueddemann et al.
patent: 4912239 (1990-03-01), Bank et al.
patent: 5300608 (1994-04-01), Chu et al.
patent: 5663269 (1997-09-01), Chu et al.

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