Catalyst system for the polymerization of olefins

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...

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502125, 502108, 526124, C08F 4656

Patent

active

053088182

ABSTRACT:
The present invention provides a catalyst system that exhibits unprecedented catalyst efficiencies and control of desired properties in the polymer product. The catalyst system includes a new generation titanium catalyst in combination with an electron donor described by the formula: ##STR1## wherein R.sub.1 is an alkyl or cycloalkyl group containing a primary or secondary carbon atom attached to the silicon atom; R.sub.2 and R.sub.3 are alkyl or aryl groups; and R.sub.4 is an alkyl or cycloalkyl group with a primary or secondary carbon atom attached to the silicon atom. The system has a catalyst efficiency of over 30 kg/g-cat.h as the Si/Ti mole ratio varies from 4-20 in the system. The system easily achieves efficiencies over 30 kg/g-cat.h. The system also exhibits good control over the xylene solubles of the polymer products.

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patent: 4970186 (1990-11-01), Terano et al.
patent: 5130284 (1992-07-01), Terano et al.
patent: 5153158 (1992-10-01), Kioka

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