Catalyst system for production of organolithium compounds and li

Details Catalyst system for production of organolithium compounds and li Catalyst system for production of organolithium compounds and li

1982-02-02

1984-06-12

Shine, W. J.

Catalyst, solid sorbent, or support therefor: product or process

Catalyst or precursor therefor

Organic compound containing

502168, 502169, B01J 3112

Patent

active

044542437

ABSTRACT:
A catalytic system is provided for the lithiation of .alpha.-olefins and .alpha.,.omega.-diolefins with concurrent production of lithium hydride. The catalysts include oxygen and sulfur containing organic compounds and polycyclic aromatics which can be combined with alkali metal and/or transition metal compounds. High yields of pure and stereospecific lithiated olefins are obtainable.

REFERENCES:
patent: 4031147 (1977-06-01), Graham
patent: 4075253 (1978-02-01), Horiie et al.

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