Catalyst system for high-cis polybutadiene

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S092000, C526S093000, C526S144000, C526S335000, C526S171000, C526S138000, C526S153000, C526S340400, C502S152000, C502S103000, C502S150000, C502S117000, C502S153000, C502S118000, C502S154000, C502S129000, C502S132000

Reexamination Certificate

active

06887956

ABSTRACT:
A catalyst system suitable for use in the production of high cis polybutadiene is disclosed. The catalyst system includes a cobalt salt of the formulaimg id="CUSTOM-CHARACTER-00001" he="2.46mm" wi="1.44mm" file="US06887956-20050503-P00900.TIF" alt="custom character" img-content="character" img-format="tif" ?CoAx?, where A is a monovalent or divalent anion and x is 1 or 2; an alkyl aluminum chloride compound of the structure R2AlCl, where R is an alkyl group containing 2-8 carbon atoms; a trialkyl aluminum compound of the formula R3Al, where R is an alkyl group containing 2-8 carbon atoms; and a catalytic amount of water.

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