Catalyst system for catalyzing the water gas shift reaction

Details Catalyst system for catalyzing the water gas shift reaction Catalyst system for catalyzing the water gas shift reaction

1977-03-31

1978-08-15

Mars, Howard T.

Compositions

Gaseous compositions

Carbon-oxide and hydrogen containing

252429R, 423655, 423656, C01B 206

Patent

active

041070763

ABSTRACT:
A method for carrying out the water gas shift reaction by use of a homogeneous catalyst system containing rhodium carbonyl iodide in a water/acetic acid solvent is described. The catalyst system can be formed from [RH (CO).sub.2 Cl].sub.2, aqueous HI and glacial acetic acid. When a reactor is charged under 250-400 torr of CO at 90.degree. C catalysis of the water gas shift reaction results.

REFERENCES:
patent: 3539298 (1970-11-01), Fenton
patent: 3718418 (1973-02-01), Fleming et al.

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