Catalyst system and process

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S096000, C526S105000, C526S106000, C526S352000

Reexamination Certificate

active

07632901

ABSTRACT:
Methods of making supported chromium catalyst systems and processes of polymerizing ethylene using the supported chromium catalyst systems are disclosed. A method of forming a catalyst system in a polymerization reactor includes contacting a supported chromium catalyst and a metal alkyl cocatalyst by cofeeding the catalyst and cocatalyst to the reactor or feeding the catalyst and cocatalyst separately to the reactor, to form a catalyst system. The catalyst and cocatalyst are not pre-contacted prior to the feeding or cofeeding step. The catalyst system can be contacted with ethylene and optional alpha-olefin comonomer to form polyethylene.

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