Catalyst system and method for carbonylation

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

Reexamination Certificate

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Details

C562S521000, C562S522000, C502S159000, C502S162000, C502S200000, C502S213000

Reexamination Certificate

active

06916954

ABSTRACT:
The invention relates to a catalyst system for carbonylating olefinically or acetylenically unsaturated compounds with carbon monoxide and a nucleophile compound, containing (a) palladium; (b) a phosphine and (c) a polymer containing nitrogen which is soluble in the reaction mixture, with the exception of polyvinyl polymers with aromatic radicals containing nitrogen on the polymer chain. The invention also relates to a method for carbonylation in the presence of one such catalyst system.

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J.Mol.Cat., Chem 143 (1999 (23-30, Bertoux et al.
J.Chem.Soc.Perkin Trans.1, 1998 1643-1655, Adler et al.

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