Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...
Patent
1980-10-01
1985-01-29
Garvin, Patrick
Catalyst, solid sorbent, or support therefor: product or process
Catalyst or precursor therefor
Plural component system comprising a - group i to iv metal...
502104, 502113, 502115, 502118, 502119, 502120, 502123, 502124, 502125, 502127, 502128, 502226, 526125, C08F 402
Patent
active
044966601
ABSTRACT:
A catalyst for polymerizing olefins is the reaction product of (A) the reaction product of (1) the reaction product of (a) an alkyl magnesium compound such as dibutylmagnesium, with (b) an oxygen-containing and/or nitrogen-containing compound such as n-propyl alcohol, or isopropylamine, with (2) a halide source such as titanium tetrachloride or silicon tetrachloride; and (B) a transition metal compound such as titanium tetrachloride and (C) a reducing agent such as triisobutylaluminum.
Also disclosed is a non-transition metal containing catalyst support for use in preparing olefin polymerization catalysts.
The polymers which are produced in the presence of this catalyst and a cocatalyst such as triethylaluminum have a low catalyst support to transition metal ratio and therefore, the catalyst efficiency based on quantity of polymer per quantity of total catalyst is very high resulting in a polymer having good color and very little, if any, corrosion.
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Ethylene Polymerization Process With a Highly Active Ziegler-Natta Catalyst: 1. Kinetics, L. L. Bohn, Polymer, vol. 19, May 1978, pp. 553-561.
Fuentes, Jr. Ricardo
Gessell Donald E.
Gibbs Ronald L.
Carter J. G.
Garvin Patrick
The Dow Chemical Company
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