Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1976-05-06
1977-08-02
Gantz, Delbert E.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
260654A, 260659A, 260662A, C07C 1715
Patent
active
040395960
ABSTRACT:
The catalyst consists essentially of a calcium fluoride matrix and a thermally stable copper-containing phase as produced by coprecipitation of calcium fluoride and copper fluoride and/or calcium hydroxide and copper oxide, in presence of alkali metal or ammonium ion. The coprecipitate is thoroughly dried and heated at elevated temperature; followed, if the coprecipitate is in the form of hydroxide and/or oxide, by conversion of such hydroxide and oxide to fluoride.
The preferred alkali metal ion is potassium.
The most active and stable catalysts show by X-ray diffraction a pattern including lines characteristic of calcium fluoride and additional lines indicative of a face-centered cubic unit cell having unit dimension of about 8.1-8.4 A.
The catalyst operates at about 200.degree.-550.degree. C. depending to some extent on the substrate.
REFERENCES:
patent: 2578913 (1951-12-01), Whitman
patent: 3591646 (1971-07-01), Vecchio et al.
Carlson Emery J.
Pieters Wim J. M.
Allied Chemical Corporation
Gantz Delbert E.
Harman Robert A.
Thierstein J.
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