Catalyst for the polymerization of olefines and processes for th

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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502125, 502108, 5261248, 5261253, 526904, C08F 4649, C08F 1006

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057475954

ABSTRACT:
A catalyst for the polymerization of olefines comprises a solid catalytic component obtained by pre-polymerizing propylene in the presence of (A) a solid component containing magnesium, titanium, halogen and an electron-donating compound, (B) an organoaluminum compound, and (C) an alkylalkoxysilane represented by the formula, R.sup.1 Si(OR.sup.2)(OCH.sub.3).sub.2, wherein R.sup.1 represents a branched or cyclic alkyl group having 3 to 6 carbon atoms, and R.sup.2 represents a branched alkyl, alkenyl or alkinyl group having 3 to 6 carbon atoms; (B) an organoaluminum compound; and (D) an alkyltrialkoxysilane represented by the formula, R.sup.3 Si(OR.sup.4).sub.2 (OCH.sub.3), wherein R.sup.3 represents a linear alkyl group having 3 to 6 carbon atoms, and R.sup.4 represents a branched alkyl, alkenyl or alkinyl group having 3 to 5 carbon atoms.

REFERENCES:
patent: 4990478 (1991-02-01), Hoppin et al.
patent: 5100981 (1992-03-01), Schreck et al.
patent: 5449738 (1995-09-01), Koura et al.
patent: 5473021 (1995-12-01), Koura et al.

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