Catalyst for the isomerization reaction of quadricyclanes to nor

Details Catalyst for the isomerization reaction of quadricyclanes to nor Catalyst for the isomerization reaction of quadricyclanes to nor

1984-12-11

1986-08-26

Brust, Joseph Paul

Catalyst, solid sorbent, or support therefor: product or process

Catalyst or precursor therefor

Organic compound containing

502163, 502167, 558383, 560128, 570151, 585353, B01J 2108, B01J 2104, B01J 2116, B01J 2376

Patent

active

046083588

ABSTRACT:
The present invention relates to a catalyst for the isomerization reaction from quadricyclanes to norbornadienes in a conversion system from light energy to heat energy which comprises cyclopropenylidene palladium complex represented by the formula, ##STR1## wherein R represents hydrogen atom, a lower alkyl or cyano group and X represents a halogen atom, and further relates to a fixed catalyst for the isomerization reaction from quadricyclanes to norbornadienes in a conversion system from light energy to heat energy which is obtained by adsorption-fixing a porphyrin Co(II) complex represented by the formula, ##STR2## wherein R.sub.2 represents a lower alkyl group and R.sub.3 represents a hydroxycarbonyl lower alkyl group, to a modified inorganic carrier in which a polyamine sulfone comprising a recurring unit represented by the formula, ##STR3## wherein R.sub.1 represents a lower alkyl group and X represents a halogen atom, has been adsorbed on a solid inorganic carrier.

REFERENCES:
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patent: 4271038 (1981-06-01), Pesa et al.
patent: 4276194 (1981-06-01), Carlson
patent: 4293442 (1981-10-01), Frame
patent: 4318825 (1982-03-01), Frame
patent: 4320029 (1982-03-01), Frame
patent: 4364843 (1982-12-01), Carlson
King, et al.; J. Org. Chem., 44, (1979), pp. 385-391.

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