Catalyst for selective conversion of synthesis gas and method of

Details Catalyst for selective conversion of synthesis gas and method of Catalyst for selective conversion of synthesis gas and method of

1985-06-05

1986-10-28

Shine, W. J.

Catalyst, solid sorbent, or support therefor: product or process

Catalyst or precursor therefor

Metal, metal oxide or metal hydroxide

502325, 502332, 502338, 518715, B01J 2104, B01J 2106, B01J 2346, B01J 2374

Patent

active

046199101

ABSTRACT:
A Fischer-Tropsch (F-T) catalyst, a method of making the catalyst and an F-T process utilizing the catalyst by which synthesis gas, particularly carbon-monoxide rich synthesis gas is selectively converted to higher hydrocarbons of relatively narrow carbon number range. In general, the selective and notably stable catalyst, consists of an inert carrier first treated with a Group IV B metal compound (such as zirconium or titanium), preferably an alkoxide compound, and subsequently treated with an organic compound of an F-T metal catalyst, such as cobalt, iron or ruthenium carbonyl. Reactions with air and water and calcination are specifically avoided in the catalyst preparation procedure.

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"The Fischer-Tropsch and Related Syntheses", Wiley, 1951, H. H. Storch et al.
Catalysis Review Science and Engineering, Poutsma, 1980, Kolbel et al., "Assessment of Advanced Process Concepts for the Liquefaction of Low H.sub.2 /CO Ratio Synthesis Gas".

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