Catalyst for reforming of methanol and process of preparing same

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide

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Details

252373, B01J 2104, B01J 2106, B01J 2310, B01J 2342, B01J 2344

Patent

active

045018235

ABSTRACT:
A catalyst for reforming of methanol to hydrogen and carbon monoxide, which is high in activity, selectivity and durability. The catalyst utilizes a granular or monolithic carrier of which the principal material is active alumina. First the carrier is coated with a mixture of cerium oxide and zirconium oxide, preferably by pyrolysis of a cerium salt and a zirconium salt applied to the carrier as a mixed solution. Then either Pt or Pd, or both, is deposited on the coated carrier preferably by pyrolysis of a platinum or palladium compound applied to the carrier as a solution. After that the nearly finished catalyst is treated with a solution of a reducing agent such as sodium boron hydride or hydrazine to render the deposited Pt and/or Pd substantially completely reduced.

REFERENCES:
patent: 4294726 (1981-10-01), Bozon et al.
patent: 4369132 (1983-01-01), Kinoshita et al.
patent: 4426319 (1984-01-01), Blanchard et al.

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