Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide
Patent
1995-12-08
1999-08-31
Lewis, Michael
Catalyst, solid sorbent, or support therefor: product or process
Catalyst or precursor therefor
Metal, metal oxide or metal hydroxide
502325, 502339, 502349, B01J 2310, B01J 2338
Patent
active
059453699
ABSTRACT:
A catalyst for purifying exhaust gases includes a porous support; a cerium oxide or a solid solution of a cerium oxide and a zirconium oxide in a state of mutual solid solution, loaded on the porous support; and a noble metal element loaded on the porous support. The cerium oxide or the solid solution has an average particle diameter of from 5 to 100 nm. The cerium oxide is present in the solid solution in an amount of from 0.2 to 4.0 by molar ratio with respect to the zirconium oxide therein. The catalyst can be prepared by: coating and calcinating on a support substrate a slurry of a cerium oxide sol, a cerium oxide sol and a zirconium oxide sol, on a solid solution powder of a cerium oxide and a zirconium oxide in a state of mutual solid solution; and loading a noble metal element thereon. The cerium oxide or its solid solution has a surface area large enough to effect an oxygen storage function, and has an average particle diameter large enough to prevent the same from entering deeply into fine pores of a porous support, thereby providing a catalyst fully exhibiting both of the oxygen storage capability and the catalytic activity.
REFERENCES:
patent: 5260249 (1993-11-01), Shiraishi et al.
patent: 5626826 (1997-05-01), Chopin et al.
Fukui Masayuki
Kandori Toshio
Kimura Mareo
Matsuoka Yoriko
Sobukawa Hideo
Ghyka Alexander G.
Kabushiki Kaisha Toyota Chuo Kenkyusho
Lewis Michael
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