Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Mixture is exhaust from internal-combustion engine
Reexamination Certificate
2001-03-05
2003-10-28
Silverman, Stanley S. (Department: 1754)
Chemistry of inorganic compounds
Modifying or removing component of normally gaseous mixture
Mixture is exhaust from internal-combustion engine
C423S239100, C423S24000R, C502S308000, C502S309000, C502S311000, C502S312000, C502S349000, C502S353000
Reexamination Certificate
active
06638486
ABSTRACT:
BACKGROUND OF THE INVENTION
A. Technical Field
The present invention relates to a catalyst for purification of exhaust gases, a production process therefor, and a process for purification of exhaust gases. Particularly, the invention relates to: a catalyst for purification of exhaust gases which catalyst is excellent as a denitrification catalyst for removing nitrogen oxides (NO
X
) from exhaust gases and as a catalyst for removing poisonous organohalogen compounds, such as dioxins, from exhaust gases; a production process therefor; and a process for purification of exhaust gases.
B. Background Art
A selective catalytic reduction process that is called SCR process is conventional as a process that is practically used at present for removing nitrogen oxides from exhaust gases wherein the selective catalytic reduction process comprises the steps of: catalytically reducing the nitrogen oxides (which are contained in the exhaust gases) on a denitrification catalyst with reducing agents such as ammonia and urea; and thereby decomposing the nitrogen oxides into harmless nitrogen and water. In recent years, as environmental pollution due to nitrogen oxides (typified by acid rain) assumes worldwide serious proportions, efficiency enhancement in denitrification arts is demanded more and more.
In such circumstances, a denitrification catalyst comprising oxides of titanium and vanadium and oxides of such as molybdenum and tungsten (JP-B-028148/1978) and a denitrification catalyst comprising a titanium-silicon-binary oxide and oxides of metals such as vanadium, tungsten, and molybdenum (JP-B-030532/1982) were put to practical use and are widely used at present.
All these catalysts have excellent ability to remove nitrogen oxides and low ability to oxidize sulfur oxides coexisting in exhaust gases, and further have excellent durability. However, it is favorable that catalysts which exhibit still higher performance emerge.
In addition, exhaust gases from incineration facilities for purification of industrial wastes and city wastes contain trace amounts of poisonous organohalogen compounds such as dioxins, PCB and chlorophenols. Particularly, the dioxins are so extremely poisonous as to have a serious influence on human bodies even if the quantities of the dioxins are very small. Therefore, a technology for removing the dioxins is desired to be developed as quickly as possible. A catalytic decomposition process is one of the most effective technologies and generally involves the use of catalysts comprising oxides of such as titanium, vanadium, tungsten and molybdenum, but, according to conditions of the exhaust gases, the performances of these catalysts cannot be said to be enough, therefore more enhancement of the catalytic performances is desired.
SUMMARY OF THE INVENTION
A. Object of the Invention
An object of the present invention is to provide: a catalyst for purification of exhaust gases which catalyst is excellent as a denitrification catalyst which has still more excellent ability to remove nitrogen oxides and of which the ability to oxidize sulfur dioxide into sulfur trioxide is extremely suppressed and further as a catalyst which is favorable for efficiently removing organohalogen compounds, such as dioxins, from exhaust gases; a production process therefor; and a process for purification of exhaust gases.
B. Disclosure of the Invention
In order to solve the above-mentioned problems, a catalyst for purification of exhaust gases, according to the present invention, comprises titanium oxide, molybdenum oxide, and vanadium oxide as catalytic components, wherein the titanium oxide and the molybdenum oxide are included in the catalyst in the form of: a binary closely mixed oxide which is beforehand prepared and includes titanium and molybdenum; and/or a trinary closely mixed oxide which is beforehand prepared and includes titanium, silicon, and molybdenum.
A production process for a catalyst for purification of exhaust gases, according to the present invention, is a production process for a catalyst for purification of exhaust gases wherein the catalyst comprises titanium oxide, molybdenum oxide, and vanadium oxide as catalytic components, and this production process comprises the steps of: mixing a titanium-compound-containing aqueous solution or slurry with a molybdenum compound and, if necessary, a silicon compound; and then removing water.
These and other objects and the advantages of the present invention will be more fully apparent from the following detailed disclosure.
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Kuma Ryoji
Masaki Shinyuki
Sugishima Noboru
Haugen Law Firm PLLP
Nippon Shokubai Co. , Ltd.
Silverman Stanley S.
Strickland Jonas N.
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