Catalyst for polymerization of ethylene, preparation thereof...

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...

Reexamination Certificate

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C502S103000, C502S104000, C502S120000, C502S128000, C502S132000, C526S124300, C526S124500, C526S125700

Reexamination Certificate

active

10533694

ABSTRACT:
The present invention provides an ethylene polymerization catalyst. The present invention also provides a process for preparing the ethylene polymerization catalyst, comprising reacting powdered magnesium with an alkyl halide of formula RX in the presence of an ether solvent to form a magnesium compound having a structure represented by the formula (RMgX)p(MgX2)q, in which R is an alkyl group having from 3 to 12 carbon atoms, X is halogen, and molar ratio of q to p is in the range of from larger than 0 to 1, impregnating the magnesium compound onto silica carrier, reacting the silica loading the magnesium compound with an alkyl halide of formula R1X, a titatium compound and an alkyl aluminum compound to form a main catalyst component, contacting the main catalyst component with a cocatalyst component to form catalyst for ethylene polymerization. The present invention also relates to the use of the catalyst in the polymerization of ethylene.

REFERENCES:
patent: 6303716 (2001-10-01), Xiao et al.
patent: 2005/0075241 (2005-04-01), Fottinger et al.
patent: A-1104220 (1995-06-01), None
patent: A-1223267 (1999-07-01), None
patent: A-1223268 (2000-07-01), None
patent: 4235405 (1994-04-01), None

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