Catalyst for oxidation

Details Catalyst for oxidation Catalyst for oxidation

1981-04-22

1983-01-18

Garvin, Patrick

Compositions

Preservative agents

Anti-oxidants or chemical change inhibitants

423584, B01J 3122

Patent

active

043691285

ABSTRACT:
A catalyst suitable for use in the synthesis of hydrogen peroxide from hydrogen and oxygen is prepared by bringing hydrogen and oxygen into contact with a liquid mixture comprising a fluorocarbon and/or halofluorocarbon and water containing bis(tri(pentafluorophenyl)phosphine) palladium dichloride. When the reaction mixture is allowed to stand the catalyst appears as a black film at the interface of the organic and aqueous phases. The black film is almost totally insoluble in aqueous hydrogen peroxide.

REFERENCES:
patent: 3336112 (1967-08-01), Hooper
patent: 4128627 (1978-12-01), Dyer et al.
patent: 4246183 (1981-01-01), Knifton
Rose et al., Condensed Chemical Dictionary, Fifth Ed. (1956) Pub. by Reinhold Pub. Corp., N.Y, N.Y., p. 494.

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