Catalyst for hydration of nitriles

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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252411R, C07C10208

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active

041783107

ABSTRACT:
Solid catalyst of reduced copper magnesium silicate type is improved for its use in catalytic hydration of acrylonitrile to make acrylamide by calcining the catalyst prior to such use. Calcining strengthens the catalyst particles for longer catalyst life in the reactor and slows the rate of decay of catalytic activity so the average productivity over the life of the catalyst is improved.

REFERENCES:
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patent: 3642643 (1972-02-01), Habermann
patent: 3645913 (1972-02-01), Habermann
patent: 3696152 (1972-10-01), Habermann et al.
patent: 3766088 (1973-10-01), Yoshimura et al.
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patent: 3795629 (1974-03-01), Newkirk et al.
patent: 3846495 (1974-11-01), Svarz
patent: 3886213 (1975-05-01), Fetchin et al.
patent: 3894962 (1975-07-01), Allain et al.
Habermann et al., CA 77:151519s (1972).
Yoshimura et al., CA 77:113835j (1972).
Kurata et al., and Tamara et al., CA 79:67043r, and 79:67049x (1973).

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