Catalyst for gas phase hydrogenation of carboxylic acids...

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

Reexamination Certificate

active

08080694

ABSTRACT:
A process for selective formation of ethanol from acetic acid includes contacting a feed stream containing acetic acid and hydrogen at an elevated temperature with catalyst comprising platinum and tin on a high surface area silica promoted with calcium metasilicate. Selectivities to ethanol of over 85% are achieved at 280° C. with catalyst life in the hundreds of hours.

REFERENCES:
patent: 2021698 (1935-11-01), Perkins
patent: 2105540 (1938-01-01), Lazier
patent: 2607807 (1952-08-01), Ford
patent: 2744939 (1956-05-01), Kennel
patent: 2882244 (1959-04-01), Milton
patent: 3130007 (1964-04-01), Breck
patent: 3478112 (1969-11-01), Adam
patent: 3702886 (1972-11-01), Araguer
patent: 3729429 (1973-04-01), Robson
patent: 4065512 (1977-12-01), Cares
patent: 4228307 (1980-10-01), Zimmerschied
patent: 4270015 (1981-05-01), Knifton
patent: 4275228 (1981-06-01), Gruffaz
patent: 4317918 (1982-03-01), Takano
patent: 4328373 (1982-05-01), Strojny
patent: 4337351 (1982-06-01), Larkins, Jr.
patent: 4374265 (1983-02-01), Larkins, Jr.
patent: 4395576 (1983-07-01), Kwantes
patent: 4398039 (1983-08-01), Pesa
patent: 4399305 (1983-08-01), Schreck
patent: 4421939 (1983-12-01), Kiff
patent: 4443639 (1984-04-01), Pesa
patent: 4465854 (1984-08-01), Pond
patent: 4471136 (1984-09-01), Larkins
patent: 4480115 (1984-10-01), McGinnis
patent: 4517391 (1985-05-01), Schuster et al.
patent: 4521630 (1985-06-01), Wattimena
patent: 4550185 (1985-10-01), Mabry
patent: 4581473 (1986-04-01), Polichnowski
patent: 4613700 (1986-09-01), Maki
patent: 4620050 (1986-10-01), Cognion
patent: 4678543 (1987-07-01), Houben
patent: 4692218 (1987-09-01), Houben
patent: 4696596 (1987-09-01), Russell
patent: 4777303 (1988-10-01), Kitson et al.
patent: 4804791 (1989-02-01), Kitson et al.
patent: 4826795 (1989-05-01), Kitson
patent: 4843170 (1989-06-01), Isshiki
patent: 4886905 (1989-12-01), Larkins, Jr.
patent: 4978778 (1990-12-01), Isshiki
patent: 4985572 (1991-01-01), Kitson
patent: 4990655 (1991-02-01), Kitson
patent: 5008235 (1991-04-01), Wegman
patent: 5061671 (1991-10-01), Kitson
patent: 5137861 (1992-08-01), Shih
patent: 5149680 (1992-09-01), Kitson
patent: 5155084 (1992-10-01), Horn
patent: 5185308 (1993-02-01), Bartley
patent: 5241106 (1993-08-01), Inoue
patent: 5243095 (1993-09-01), Roberts
patent: 5306845 (1994-04-01), Yokohama
patent: 5350504 (1994-09-01), Dessau
patent: 5426246 (1995-06-01), Nagahara
patent: 5475144 (1995-12-01), Watson
patent: 5476827 (1995-12-01), Ferrero
patent: RE35377 (1996-11-01), Steinberg
patent: 5585523 (1996-12-01), Weiguny
patent: 5691267 (1997-11-01), Nicolau
patent: 5719315 (1998-02-01), Tustin
patent: 5731456 (1998-03-01), Tustin
patent: 5767307 (1998-06-01), Ramprasad
patent: 5821111 (1998-10-01), Grady
patent: 5849657 (1998-12-01), Rotgerink
patent: 5861530 (1999-01-01), Atkins
patent: 5945570 (1999-08-01), Arhancet
patent: 5955397 (1999-09-01), Didillon
patent: 5973193 (1999-10-01), Crane
patent: 6040474 (2000-03-01), Jobson
patent: 6049008 (2000-04-01), Roberts
patent: 6093845 (2000-07-01), van Acker
patent: 6114571 (2000-09-01), Abel
patent: 6121498 (2000-09-01), Tustin
patent: 6232352 (2001-05-01), Vidalin
patent: 6232504 (2001-05-01), Barteau
patent: 6294703 (2001-09-01), Hara
patent: 6462231 (2002-10-01), Yanagawa
patent: 6472555 (2002-10-01), Choudary
patent: 6486366 (2002-11-01), Ostgard
patent: 6495730 (2002-12-01), Konishi
patent: 6509180 (2003-01-01), Verser
patent: 6509290 (2003-01-01), Vaughn
patent: 6559333 (2003-05-01), Brunelle
patent: 6603038 (2003-08-01), Hagemeyer
patent: 6632330 (2003-10-01), Colley
patent: 6657078 (2003-12-01), Scates
patent: 6685754 (2004-02-01), Kindig
patent: 6693213 (2004-02-01), Kolena
patent: 6696596 (2004-02-01), Herzog
patent: 6727380 (2004-04-01), Ellis
patent: 6765110 (2004-07-01), Warner
patent: 6768021 (2004-07-01), Horan
patent: 6812372 (2004-11-01), Janssen
patent: 6852877 (2005-02-01), Zeyss
patent: 6903045 (2005-06-01), Zoeller
patent: 6906228 (2005-06-01), Fischer
patent: 6927048 (2005-08-01), Verser
patent: 7074603 (2006-07-01), Verser
patent: 7084312 (2006-08-01), Huber
patent: 7297236 (2007-11-01), Vander Griend
patent: 7351559 (2008-04-01), Verser
patent: 7375049 (2008-05-01), Hayes
patent: 7425657 (2008-09-01), Elliott
patent: 7507562 (2009-03-01), Verser
patent: 7538060 (2009-05-01), Barnicki
patent: 7553397 (2009-06-01), Colley
patent: 7572353 (2009-08-01), Vander Griend
patent: 7608744 (2009-10-01), Johnston
patent: 7863489 (2011-01-01), Johnston
patent: 7884253 (2011-02-01), Stites
patent: 2003/0013908 (2003-01-01), Horan
patent: 2003/0077771 (2003-04-01), Verser
patent: 2003/0104587 (2003-06-01), Verser
patent: 2003/0114719 (2003-06-01), Fischer
patent: 2003/0191020 (2003-10-01), Bharadwaj
patent: 2004/0195084 (2004-10-01), Hetherington
patent: 2006/0019360 (2006-01-01), Verser
patent: 2006/0102520 (2006-05-01), Lapinski
patent: 2006/0106246 (2006-05-01), Warner
patent: 2006/0127999 (2006-06-01), Verser
patent: 2007/0270511 (2007-11-01), Melnichuk
patent: 2008/0207953 (2008-08-01), Houssin
patent: 2009/0005588 (2009-01-01), Hassan
patent: 2009/0023192 (2009-01-01), Verser
patent: 2009/0081749 (2009-03-01), Verser
patent: 2009/0166172 (2009-07-01), Casey
patent: 2009/0221725 (2009-09-01), Chornet
patent: 2009/0326080 (2009-12-01), Chornet
patent: 2010/0029995 (2010-02-01), Johnston
patent: 2010/0113843 (2010-05-01), Lee
patent: 2010/0121114 (2010-05-01), Weiner
patent: 2010/0168493 (2010-07-01), Le Peltier
patent: 2010/0196789 (2010-08-01), Fisher
patent: 2010/0249479 (2010-09-01), Berg-Slot
patent: 1230458 (1999-10-01), None
patent: 0137749 (1985-04-01), None
patent: 0167300 (1986-01-01), None
patent: 0175558 (1986-03-01), None
patent: 0192587 (1986-08-01), None
patent: 0372847 (1990-06-01), None
patent: 0408528 (1991-01-01), None
patent: 0198682 (1991-03-01), None
patent: 0285786 (1993-05-01), None
patent: 0990638 (2000-04-01), None
patent: 1262234 (2002-12-01), None
patent: 1277826 (2003-01-01), None
patent: 2060553 (2009-05-01), None
patent: 2060555 (2009-05-01), None
patent: 0400904 (2009-12-01), None
patent: 2186787 (2010-05-01), None
patent: 1168785 (1969-10-01), None
patent: 1559540 (1980-01-01), None
patent: 2136704 (1984-09-01), None
patent: 6116182 (1994-04-01), None
patent: 10306047 (1998-11-01), None
patent: 11147845 (1999-06-01), None
patent: 2001046874 (2001-02-01), None
patent: 2001157841 (2001-06-01), None
patent: 83003409 (1983-10-01), None
patent: 03040037 (2003-05-01), None
patent: 2005102513 (2005-01-01), None
patent: 2009009322 (2009-01-01), None
patent: 2009009323 (2009-01-01), None
patent: 2009063176 (2009-05-01), None
patent: 2009086839 (2009-07-01), None
patent: 2009105860 (2009-09-01), None
patent: 2010014145 (2010-02-01), None
patent: 2010014151 (2010-02-01), None
patent: 2010014153 (2010-02-01), None
patent: 2010055285 (2010-05-01), None
English langauge abstract for EP 0 192 587 A1.
English language abstract for EP 0 137749 A2.
English language abstract for JP 2001-157841 A.
English language abstract for JP 2001-046874 A.
English language abstract for JP 10-306047 A.
Zheng, et al. (2007). Preparation and catalytic properties of a bimetallic Sn-Pt complex in the supercages of NaY zeolite by use of surface organometallic chemistry, Applied Organometallic Chemistry, 21(10), 836-840.
ZeaChem, Inc., Technology Overview, Lakewood, Colorado www.zeachem.com, 2008.
Santori et al. (2000). Hydrogenation of carbonylic compounds on Pt/SiO2 catalysts modified with SnBu4, Studies in Surface Science and Catalysis, 130, 2063-2068.
Rachmady, Acetic Acid Reduction by H2 on Bimetallic Pt Fe Catalysts, Journal of Catalysis 209, 87-98 (Apr. 1, 2002), Elsevier Science (USA).
Pestman et al., The formation of ketones and aldehydes from carboxylic acids, structure-activity relationship for two competitive reactions, Journal of Molecular Catalysis A: Chemical 103 Jun. 14, 1995, 175-180.
Pestman et al., (1997). Reactions of Carboxylic Acids on Oxides, Journal of Catalysis 168, 255-264.
Pestman et al., (1998). Identification of the Active Sites in the Selective Hydrogenation of Acetic Acid to Acetaldehyde on Iron Oxid

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Catalyst for gas phase hydrogenation of carboxylic acids... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Catalyst for gas phase hydrogenation of carboxylic acids..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Catalyst for gas phase hydrogenation of carboxylic acids... will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-4267777

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.