Catalyst for bisalkoxycarbonylation of olefins, and method for p

Details Catalyst for bisalkoxycarbonylation of olefins, and method for p Catalyst for bisalkoxycarbonylation of olefins, and method for p

1999-06-14

2000-12-12

Wood, Elizabeth

Catalyst, solid sorbent, or support therefor: product or process

Catalyst or precursor therefor

Organic compound containing

502150, 502152, 502154, 502155, 502156, 502165, B01J 3124, B01J 3128, B01J 3130

Patent

active

061598917

ABSTRACT:
A catalyst for the bisalkoxycarbonylation of olefins comprising a noble metal compound and a phosphine chalcogenide of the following formula (1): ##STR1## wherein each of R.sup.1, R.sup.2 and R.sup.3 is, independently, an alkyl group or an aryl group each of which may have a substituent, and A is a Group 16 element of the Periodic Table; and R.sup.1, R.sup.2 or R.sup.3 may be combined, directly or through a bridging group, with one another where the groups to be combined may be attached either to an identical phosphorus atom or to different phosphorus atoms. Element A includes oxygen, sulfur and selenium atoms. The noble metal compound includes palladium(II) halides and other palladium compounds. The catalyst may further include a copper (I) halide or other copper compound as a co-catalyst. The use of this catalyst can provide the bisalkoxycarbonylation of olefins with efficiency.

REFERENCES:
patent: 4333852 (1982-06-01), Warren
patent: 4414160 (1983-11-01), Erpenbach et al.
patent: 4730080 (1988-03-01), Drent
patent: 5030712 (1991-07-01), Van Doorn et al.
patent: 5137857 (1992-08-01), Van Doorn
Journal of the American Chemical Society /98:7/Mar. 31, 1976 pp. 1806-1809.
Journal of Molecular Catalysis A:Chemical 111 (1996) L3-L6 No Month Available.
J. Chem. Soc. Perkin Trans. 1, (1993) pp. 1031-1037 No Month Available.
J. Org. Chem. (1992), 57, 4189-4194 No Month Available.
J. Org. Chem., vol. 37, No. 12, (1972) pp. 2034-2035 No Month Available.
Bull. Chem. Soc. Jpn 64, 3600-3606(1991) vol. 64, No. 12 No Month Available.
Tetrahedron Letters, vol. 28, No. 3, pp. 325-328, (1987) No Month Available.
Journal of the American Chemical Society /98:7/Mar. 31, 1976 pp. 1810-1823.
Angew.Chem. Int.Ed. Engl. (1993), 32 No. 12 pp. 1719-1720 No Month Available.
Organometallics (1992), 11, 1975-1978 No Month Available.
Bull. Chem. Soc. Jpn., 69, 735-742 (1996) No Month Available.
Tetrahedron Letters vol. 39, No. 41 Oct. 8, 1998 pp. 7529-7532.

Affiliated with

Also associated with

Rating

Catalyst for bisalkoxycarbonylation of olefins, and method for p does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Catalyst for bisalkoxycarbonylation of olefins, and method for p, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Catalyst for bisalkoxycarbonylation of olefins, and method for p will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-216734