Catalyst comprising potassium and cesium pyrosulfates with vanad

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Sulfur or compound containing same

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502242, 502350, 549249, B01J 27055, B01J 2106, C07D30789

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active

049314181

ABSTRACT:
Catalyst compositions are disclosed containing potassium pyrosulfate, cesium pyrosulfate, supported on an inorganic oxide. The catalysts will selectively oxidize naphthalene and/or o-xylene to phthalic anhydride in a fluidized- or fixed-bed reactor system. Sulfur-containing gaseous promoter may be fed with the aromatic hydrocarbon to enhance selectivity.

REFERENCES:
patent: 2458818 (1949-01-01), Young
patent: 3565919 (1971-02-01), Friedrichsen et al.
patent: 3692699 (1972-09-01), Hojo et al.
patent: 3810921 (1974-05-01), Maselli et al.
patent: 3862960 (1975-01-01), Cheavens et al.
patent: 3926846 (1975-12-01), Ono et al.
patent: 3948807 (1976-04-01), Fuchigami et al.
patent: 4046780 (1977-09-01), Nakamishi et al.
patent: 4096094 (1978-06-01), Blechschmitt et al.
patent: 4196101 (1980-04-01), Wilson et al.
patent: 4284571 (1981-08-01), Sato et al.
patent: 4382022 (1983-05-01), McDaniel
patent: 4424320 (1984-01-01), McDaniel
patent: 4481304 (1984-11-01), Sato et al.
patent: 4482643 (1984-11-01), Harju et al.
patent: 4489204 (1984-12-01), Heri et al.
patent: 4705770 (1985-11-01), Cullo et al.
Sembaev et al, "Principles for the Selection of Vanadium Oxide Catalysts for Partial Oxidation and Oxidative Ammonolysis of Aromatic Compounds", Geterog. Katal., Mater. Vses. Konf. Mekh. Katal, Reakts., 3rd, 1981 (Published 1982), pp. 58-61.
Montgomery, "Oxidation of Ortho-Xylene Over Alkali Metal Promoted Vanadia-Titania Catalysts", W. R. Grace & Co., Baltimore, Md., 2 sheets.
Haase et al, "Quick Screening Method for Industrial Phthalic Anhydride Catalysts", Applied Catalysis, 19(1985), pp. 13.19, Elsevier Science Publ. Amsterdam.
Saleh et al, "Comparison of V.sub.2 O.sub.5 /TiO.sub.2 (Anatase) and V.sub.2 O.sub.5 /TiO.sub.2 (Rutile): Promoting Effect of the Support", American Chemical Society, N.Y. Meeting, Apr. 13-18, 1986, pp. 272-276.
Rusiecka et al, "O-Xylene Oxidation on V.sub.2 O.sub.5 -TiO.sub.2 Oxide System, II., ESR Studies of the Catalysts", Applied Catalysis, 10(1984), pp. 101-110, Elsevier Science Publ.-/Amsterdam.
Gasior et al, "O-Xylene Oxidation on the V.sub.2 O.sub.5 -TiO.sub.2 Oxide System, I. Dependence of Catalytic Properties on the Modification of TiO.sub.2 ", Applied Catalysis, 10(1984), pp. 87-100, Elsevier Science Publ.-Amsterdam.

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