Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1979-03-12
1980-06-03
Mars, Howard T.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
2604496M, 252456, 252444, 252463, 252473, 252474, C07C 104
Patent
active
042061350
ABSTRACT:
An improved method for the enhanced synthesis of paraffinic hydrocarbons with chain lengths of from 2 to 6 carbon atoms inclusive with reduced methane formation which method comprises the steps of passing a synthesis gas stream comprising CO and H.sub.2 over a catalyst at a temperature and pressure for a time sufficient to generate the desired C.sub.2 -C.sub.6 paraffinic product, wherein the catalyst comprises from about 0.01 to about 15 wt. % nickel on a support selected from the group consisting of tantalum oxides, niobium oxides, and other tantalum or niobium containing oxides and mixtures thereof. The nickel average crystallite size is preferably less than 5 nm (50 A). The supported nickel catalyst has a BET surface area of from about 10 to 60 m.sup.2 /g.
REFERENCES:
patent: 3158567 (1964-11-01), Cole et al.
patent: 3228892 (1966-11-01), Cole et al.
Kugler Edwin L.
Tauster Samuel J.
Allocca Joseph J.
Exxon Research & Engineering Co.
Mars Howard T.
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