Catalyst comprising a modified solid oxide

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide

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502326, 502333, 502334, 502335, 502336, 502349, 502350, 502352, B01J 2300, B01J 2342, B01J 2340

Patent

active

057190976

ABSTRACT:
There is provided a catalyst comprising a hydrogenation/dehydrogenation component, such as a noble metal, and an acidic solid component comprising a Group IVB metal oxide modified with an oxyanion of a Group VIB metal. An example of this catalyst is zirconia, modified with tungstate and platinum. There is also provided a method for preparing this catalyst. This catalyst may be used, for example, to isomerize C.sub.4 to C.sub.8 paraffins. The feed to this paraffin isomerization reaction may, optionally, include cyclic hydrocarbons, such as benzene or cyclohexane, which may undergo ring opening reactions during the course of the isomerization reaction.

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Hsu C.Y., Heimbuch, C.R., Armes, C.T., and Gates, B.C., A Highly Active Solid Superacid Catalyst for n-Butane Isomerization: a Sulfated Oxide Containing Iron, Manganese and Zirconium, J. Chem. Soc., Chem. Commun., 1645 (1992) No Month Available.
Hino, M. et al., "Synthesis of Solid Superacid of Tungsten Oxide Supported On Zirconia and its Catalytic Action for Reactions of Butane and Pentane," J.Chem.Soc., Chem. Commun., 1259-1260 (1988) No Month Available.
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