Catalyst comprising a metal complex of the VIII subgroup...

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Organic compound containing

Reexamination Certificate

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C502S167000, C558S335000, C558S338000, C558S339000, C558S340000, C568S429000, C568S454000, C568S455000, C568S456000

Reexamination Certificate

active

06852661

ABSTRACT:
A catalyst comprising at least one complex of a metal of transition group VIII comprising at least one monodentate, bidentate or multidentate phosphinamidite ligand in which the phosphorus atom and the oxygen atom of the phosphinamidite group form part of a 5- to 8-membered heterocycle can be used for the hydroformylation and hydrocyanation of compounds containing at least one ethylenically unsaturated double bond. The phosphinamidite ligand is, for example, represented by the following formulaewhereinrepresents an optionally substituted 5- to 8-membered heterocycle wherein A represents carbon ring members;represents an optionally substituted N-bonded heterocycle wherein (Het) indicates optional ring heteroatoms in addition to the N; andB is a carbon-carbon single bond or a divalent bridging group.

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