Catalyst compositions of transition metal carbonyl complexes int

Details Catalyst compositions of transition metal carbonyl complexes int Catalyst compositions of transition metal carbonyl complexes int

1980-11-17

1982-04-13

Niebling, John F.

Compositions

Preservative agents

Anti-oxidants or chemical change inhibitants

252443, 423655, 568451, 568883, C01B 102, C01B 206

Patent

active

043246958

ABSTRACT:
Transition metal carbonyl clusters intercalated with lamellar material such as graphite or smectites are prepared by reacting an intercalate of a transition metal halide with carbon monoxide at elevated temperature and at ambient to superatmospheric pressure. The intercalated complexes are useful in the catalysis of a variety of organic reactions including the water gas shift reaction, hydrogenation, hydroformylation, methanation, and so forth.

REFERENCES:
patent: 3804916 (1974-04-01), Lalancette
patent: 3835067 (1974-09-01), Schneider
patent: 3847963 (1974-11-01), Lalancette
patent: 4207245 (1980-06-01), Halbert
patent: 4226845 (1980-10-01), Laine

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