Catalyst compositions for the selective conversion of...

Organic compounds -- part of the class 532-570 series – Organic compounds – Nitriles

Reexamination Certificate

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C568S910000, C568S959000, C502S311000, C502S312000, C502S317000, C502S321000, C502S347000, C502S353000, C502S354000, C502S348000, C502S300000, C502S324000, C502S303000, C502S304000, C502S308000, C502S310000, C502S349000, C502S352000, C502S313000, C502S316000, C502S325000, C502S338000, C502S344000, C502S319000, C502S322000, C502S323000, C502S355000, C502S208000, C502S209000, C502S211000

Reexamination Certificate

active

06919472

ABSTRACT:
A catalyst composition for the selective conversion of an alkane to an unsaturated carboxylic acid having the general formula:in-line-formulae description="In-line Formulae" end="lead"?MoVaNbbAgcMdOxin-line-formulae description="In-line Formulae" end="tail"?wherein optional element M may be one or more selected from aluminum, copper, lithium, sodium, potassium, rubidium, cesium, gallium, phosphorus, iron, rhenium, cobalt, chromium, manganese, arsenic, indium, thallium, bismuth, germanium, tin, cerium or lanthanum; a is 0.05 to 0.99, b is 0.01 to 0.99, c is 0.01 to 0.99, d is 0 to 0.5 and x is determined by the valence requirements of the other components of the catalyst composition. This catalyst is prepared by co-precipitation of compounds of molybdenum, vanadium, niobium, silver and M to form a mixed metal oxide catalyst. This catalyst can be used for the selective conversion of an alkane to an unsaturated carboxylic acid in a one-step process or the ammoxidation of alkanes and olefins.

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