Catalyst compositions especially useful for preparation of unsat

Compositions – Preservative agents – Anti-oxidants or chemical change inhibitants

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252435, 252462, 252464, 252465, 252468, 252469, 252470, 260530N, B01J 2714, B01J 2310, B01J 2314, B01J 2316

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041014480

ABSTRACT:
The present invention relates to a catalyst composition consisting of oxide complexes of vanadium, molybdenum and germanium plus an additional oxide selected from the group consisting of iron, nickel, thallium, phosphorus, indium, bismuth and the rare earths and optionally an oxide selected from the group copper, magnesium, manganese, aluminum, titanium, potassium, rubidium, cesium, niobium, tantalum, chromium, tungsten, uranium, cobalt, silver, zinc, tin, gallium, arsenic and antimony. These catalysts are especially useful for producing acrylic acid from acrolein and for producing methacrylic acid from methacrolein.

REFERENCES:
patent: 3736354 (1973-05-01), Yanagita et al.
patent: 3875220 (1975-04-01), White et al.
patent: 3882047 (1975-05-01), Niina et al.
patent: 3956181 (1976-05-01), Grasselli et al.
patent: 3965163 (1976-06-01), Oda et al.

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