Catalyst compositions derived from titanium-containing molecule

Catalyst – solid sorbent – or support therefor: product or process – Zeolite or clay – including gallium analogs – And additional al or si containing component

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502 73, 502 85, 502215, 502242, 423326, 423713, 423DIG22, 423DIG27, 423DIG29, 423DIG33, B01J 2106, C01B 3926

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active

059770090

ABSTRACT:
Useful catalyst compositions are produced by treating substituted molecular sieves with reactive titanium compounds such as titanium tetrahalides, preferably in the vapor phase at elevated temperatures. The molecular sieve starting materials contain tellurium, boron or germanium oxides in addition to silicon and titanium oxides. Olefins are efficiently transformed to epoxides using these catalyst compositions and an oxidizing agent such as hydrogen peroxide or an organic hydroperoxide.

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