Catalyst compositions and their use in the preparation of releas

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From silicon reactant having at least one...

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260 332SB, 252429R, 252431R, 252431N, 252431P, 252431C, 427387, 528 31, 528 32, C08G 7706

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active

042810930

ABSTRACT:
A catalyst composition comprising a solution of an organo-metallic complex of platinum or rhodium in a liquid allyl ether which has a b.p. of at least 150.degree. C. at 1 bar and which is free from groups having an adverse effect on the catalytic affect of the complex; polyorganosiloxane coating compositions containing a Si--H polysiloxane and a polysiloxane containing Si--OH, Si-vinyl or Si-allyl groups, an organo-metallic complex of platinum or rhodium and an allyl ether as defined above; and the use of the compositions for preparing release coatings on substrates.
In the coating of substrates, especially paper, with release coatings based on heat-curable polysiloxane compositions, organo-metallic complexes of platinum or rhodium can be used as catalysts provided they are dissolved in the composition. The low-boiling solvents hitherto used have disadvantages in causing atmospheric pollution and requiring solvent-recovery plant. The ethers defined can be used in place of the low-boiling solvents to give satisfactory coatings without the mentioned disadvantages.

REFERENCES:
patent: 3936581 (1976-02-01), Garden
patent: 3960810 (1976-06-01), Chandra et al.
patent: 4064154 (1977-12-01), Chandra et al.
patent: 4108833 (1978-08-01), Hatanaka et al.
patent: 4123604 (1978-10-01), Sandford, Jr.
patent: 4162356 (1979-07-01), Grenoble

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