Catalyst composition polymerization of isoolefins and multiolefi

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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252429R, 252431R, C08F 452

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042699550

ABSTRACT:
The present invention relates to improved catalyst compositions used in the formation of substantially gel-free copolymers and terpolymers of isobutylene and one or more dienes having an Mn of about less than 500,000, a mole % unsaturation of about 8 to about 45, and a polydispersity value of about 3 to about 30, wherein the mixture of isobutylene and diene monomers and a cosolvent are contacted with the catalyst composition at polymerization conditions (-50.degree. to -100.degree. C.) wherein the improvement includes the hydrocarbon soluble catalyst composition being formed from the reaction product of a material of the formula:

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