Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof
Patent
1997-08-20
1999-05-04
Mosley, Terressa
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
From carboxylic acid or derivative thereof
C08G 6400
Patent
active
059004746
ABSTRACT:
The invention relates to a process of producing polybutylene terephthalate by direct esterification and then melt polycondensation, characterized in that a specific catalyst composition is used, said catalyst composition comprising an organotitanium compound as primary catalyst in an amount of 0.01 to 1.0% by weight of terephthalic acid; and an alkaline metal salt of borate, pyroborate or metaborate as secondary catalyst in an amount of 0.001 to 1.0% by weight of terephthalic acid. By using said catalyt composition, amount of THF by-product generated can be reduced more than 30%, and the reaction rate of esterification can be increased over 20%.
(FIG. 2)
REFERENCES:
patent: 4107149 (1978-08-01), Bier et al.
patent: 4136089 (1979-01-01), Bier et al.
Lin Ching-Shian
Wang Chun-Shan
Mosley Terressa
National Science Council of Republic of China
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