Catalyst composition and method for producing diaryl carbonates

Organic compounds -- part of the class 532-570 series – Organic compounds – Carbonate esters

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558271, 558272, 558273, C07C 6800

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active

061145645

ABSTRACT:
Hydroxyaromatic compounds such as phenol are carbonylated with oxygen and carbon monoxide in the presence of a catalyst system comprising a Group VIII metal having an atomic number of at least 44, preferably palladium; an alkali metal or alkaline earth metal halide, preferably sodium bromide; and at least one aliphatic polyether such as a polyethylene glycol dimethyl ether or a crown ether. The catalyst system also preferably contains a compound of another metal, preferably lead.

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