Catalyst and process of production of polyethylene

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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252429B, 252429C, 252431R, 526119, 526122, 526127, 526128, 526132, 526144, 526151, 526165, 526352, C08F 466, C08F 1002

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039898784

ABSTRACT:
A process for polymerizing ethylene or a mixture of ethylene and another olefin is proposed in which the polymerization can be carried out with an extremely high efficiency by using a catalyst prepared by reacting (A) a hydrocarbon-insoluble reaction product (obtained by reacting (i) a specified organomagnesium-containing hydrocarbon-soluble complex, or reaction product of (i), with (ii) a specified siloxane compound and with (iii) at least one kind of titanium or vanadium compound containing at least one halogen atom), with (B) a specified organoaluminum compound. Resultant polymers have a high molecular weight and a high rigidity and molecular weight and molecular weight distribution thereof can be easily controlled.

REFERENCES:
patent: 3737393 (1973-06-01), de Vries
patent: 3755274 (1973-08-01), Piekarski et al.
patent: 3907759 (1975-09-01), Okada et al.

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