Catalyst and process for the preparation of ethylene and vinyl c

Details Catalyst and process for the preparation of ethylene and vinyl c Catalyst and process for the preparation of ethylene and vinyl c

1976-03-24

1978-07-25

Gantz, Delbert E.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260683R, 2606833, C07C 2102

Patent

active

041029364

ABSTRACT:
Ethane is reacted with oxygen and a chlorine source in the presence of a solid solution catalyst containing iron cations which is stabilized with lanthanum and/or lanthanides and modified with selected metal cations, to yield ethylene, vinyl chloride, and other valuable by-products. Conversion of ethane to products approaches 100 percent, ethylene is prepared in up to 90 mole percent yield, and the combined yield of ethylene, vinyl chloride and ethyl chloride is over 90 mole percent.

REFERENCES:
patent: 3207811 (1965-09-01), Bojars
patent: 3274285 (1966-09-01), Bojars
patent: 3769362 (1973-10-01), Beard
patent: 3904553 (1975-09-01), Campbell et al.

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