Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...
Patent
1998-02-04
1999-11-16
Wood, Elizabeth D
Catalyst, solid sorbent, or support therefor: product or process
Catalyst or precursor therefor
Plural component system comprising a - group i to iv metal...
500102, 500103, 500114, 500115, 502116, 502117, 526943, B01J 3100
Patent
active
059857846
ABSTRACT:
A highly effective catalyst system for the polymerization or copolymerization of olefins comprises at least one metallocene as transition-metal compound and at least one aluminum compound of the formula II ##STR1## and/or of the formula (III) ##STR2## where, in the formulae (II) and (III), the radicals R.sup.14 may be identical or different and are an alkyl group, an aryl group, benzyl or hydrogen, and p is an integer from 2 to 50, and at least one aluminum compound of the formula IV ##STR3## where R.sup.15, R.sup.16 and R.sup.17 are identical or different and are a hydrogen atom, an alkyl group, an alkylsilyl group, an alkoxy group, an aryl group, an aryloxy group, an alkenyl group, an arylalkyl group, an alkylaryl group, an arylalkenyl group, a halogen atom or a radical of the formula --OSiR.sup.15 R.sup.16 R.sup.17 where R.sup.15, R.sup.16 and R.sup.17 are as defined in the description.
REFERENCES:
patent: 3709853 (1973-01-01), Karapinka et al.
patent: 4701432 (1987-10-01), Welborn et al.
patent: 4769510 (1988-09-01), Kaminsky et al.
patent: 4794096 (1988-12-01), Ewen et al.
patent: 4874734 (1989-10-01), Kioka et al.
patent: 4962262 (1990-10-01), Winter et al.
patent: 5122491 (1992-06-01), Kioka et al.
patent: 5308816 (1994-05-01), Tsutsui et al.
patent: 5308817 (1994-05-01), Reddy et al.
patent: 5369196 (1994-11-01), Matsumoto et al.
patent: 5416178 (1995-05-01), Winter et al.
patent: 5498582 (1996-03-01), Krause et al.
patent: 5561092 (1996-10-01), Ewen et al.
Xinmin Yang et al., "Cation-like Homogeneous Olefin Polymerization Catalysts Based Upon Zirconocene Alkyls and Tris(pentafluorophenyl)borane", J. Am. Chem. Soc. 1991, 113, pp. 3623-3625. no month.
Resconi, L., et al., "Macromolecules", vol. 23, (1990), pp. 4489-4491. no month.
Chien, J.C.W., et al., J.Poly. Sci., Part A, Pol., Chem. 29 (1991) pp. 459-470. no month.
Journal of Polymer Science/Part A Polymer Chemistry, Chien et al., Metallocene-Methylaluminoxane Catalysts for Olefin Polymerization I. Trimethylaluminum as Coactivator, Oct. 1988, vol. 26, pp. 3089-3102. no month.
G. B. Hiatky et al, J. Am. Chem Soc 111, pp. 2728-2729 (1989). no month.
Sinn et al., "Ziegler-Natta Catalysis", Advances in Organometallic Chemistry, vol. 18, (1980) pp. 99-149. no month.
Ewen, J.A., et al., J.Am. Chem. Soc., vol. 109 (1987) pp. 6544-6545. no month.
Dolle Volker
Spaleck Walter
Winter Andreas
Targor GmbH
Wood Elizabeth D
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