Catalyst and process for production of cinnamates

Details Catalyst and process for production of cinnamates Catalyst and process for production of cinnamates

1984-12-21

1988-04-12

Killos, Paul J.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

560 55, 560 21, 560 20, 560 75, 560102, C07C 6976

Patent

active

047375914

ABSTRACT:
A method of preparing esters of cinnamic acid comprising catalytically reacting a styrene compound with carbon monoxide, oxygen, and an aliphatic alcohol. The catalyst is essentially a combination of a palladium (II) compound and a copper salt. A catalytic amount of a dehydrating agent may be present to increase the selectivity of the reaction.

REFERENCES:
patent: 3346625 (1967-10-01), Fenton et al.
patent: 3381030 (1968-04-01), Biale et al.
patent: 3437676 (1969-04-01), von Kutepow
patent: 3530168 (1970-09-01), Biale

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