Catalyst and method of broadening polymer molecular weight distr

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526113, 526118, 526119, 526127, 526160, 5263486, 526352, 502113, 502152, C08F 234, C08F 464

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052816796

ABSTRACT:
A catalyst and method of producing polyolefins having broadened molecular weight distributions and enhanced tensile impact strengths utilizing a silica supported metallocene-alumoxane catalyst system, wherein at least one of the metallocenes has at least one cyclopentadienyl ring being substituted by at least one optionally substituted hydrocarbon substituent having a 2.degree. or 3.degree. carbon atom with which it is covalently bonded to the cyclopentadienyl ring.

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patent: 4935474 (1990-06-01), Ewen et al.
patent: 4937301 (1990-06-01), Chang
patent: 5132262 (1992-07-01), Rieger et al.

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