Catalyst activators, processes for making same, and use...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C502S103000, C502S120000, C502S152000, C502S156000, C502S167000, C502S224000, C526S127000, C526S143000, C526S147000, C526S160000

Reexamination Certificate

active

07928172

ABSTRACT:
Compositions useful for activating catalysts for olefin polymerization are-provided. The compositions are derived from at least: a) compound derived from at least (i) carrier having at least one pair of hydrogen bonded hydroxyl groups, (ii) organoaluminum compound, and (iii) Lewis base, such that each of a majority of aluminum atoms in the organoaluminum compound forms chemical bonds with at least two oxygen atoms from the at least one pair of hydrogen bonded hydroxyl groups; and b) Bronsted acid, wherein the molar ratio of the Bronsted acid to the organoaluminum compound is less than or equal to about 2:1.

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Russell A. Stapleton, et al; Bulky Aluminum Alkyl Scavengers In Olefin Polymerization With Group 4 Catalysts; Journal Of The American Chemical Society; 2003; p. 9246-9247; vol. 125; American Chemical Society, Washington DC, US.

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