Catalyst activation process

Catalyst – solid sorbent – or support therefor: product or process – Regenerating or rehabilitating catalyst or sorbent – Gas or vapor treating

Reexamination Certificate

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Details

C518S709000

Reexamination Certificate

active

06919290

ABSTRACT:
A process for activating a cobalt-containing catalyst by contacting the catalyst with hydrogen in a reaction system suitable for use in a Fischer-Tropsch synthesis wherein a first gaseous stream comprising 0.25 to 5% by volume of hydrogen and 95 to 99.75% by volume of inert gas is continuously introduced into the reaction system and a second gaseous stream is continuously withdrawn from the reactor system wherein the activation procedure comprises the steps of: (A) heating the contents of the reactor system to a temperature which is in a range of 25 to 5° C. below a critical activation temperature; (B) thereafter increasing the temperature at a rate of up to 20° C. per hour to a first hold temperature which is in a range of from the critical activation temperature to a temperature which is at most 20° C. above the critical activation temperature; and (C) maintaining the contents of the reactor system approaches the hydrogen content of the first gaseous stream.

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patent: 6100304 (2000-08-01), Singleton et al.
patent: 6130184 (2000-10-01), Geerlings et al.
patent: 6465529 (2002-10-01), Daage et al.
patent: 6475943 (2002-11-01), Hoek et al.
patent: 6486220 (2002-11-01), Wright
patent: 6509382 (2003-01-01), Ducreux et al.
patent: 6537945 (2003-03-01), Singleton et al.
patent: 0590882 (1993-09-01), None
patent: WO9717137 (1997-05-01), None
patent: WO 99/61550 (1999-12-01), None

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