Catalyst

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide

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502339, B01J 2310, B01J 2340

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active

054808545

ABSTRACT:
A reaction comprising the oxidation of carbon monoxide to carbon dioxide, eg in vehicle exhausts, employs a catalyst composed of metal oxide, eg ceria, particles among which are uniformly incorporated noble metal particles, the particles having such a high interaction that, without hydrogen reduction pre-treatment, the catalyst exhibits the formation of anionic vacancies on the metal oxide surface at a temperature lower than does the corresponding catalyst prepared by impregnation. The catalyst employed is preferably prepared by co-precipitation.

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Journal of Catalysts, `Ceria in Automotive Exhaust Catalysts`, Yao et al., 86, (1984), pp. 254-265.
Catalysis and Automotive Pollution Control II, `The Role of Ceria in Three-Way Catalysts`, edited by A. Crucq, published by Elsevier Science Publishers B.V., Amsterdam (1991), pp. 139-152.
J. Chem. Soc. Faraday Trans., 1991, 87(17), `Carbon Dioxide Hydrogenation over Au/ZrO.sub.2 Catalysts from Amorphous Precursors: Catalytic Reaction Mechanism`, Koeppel et al., pp. 2821-2828.
Journal of Catalysts, `Comparison of the Performance Characteristics of Pt/SnO.sub.x and Au/MnO.sub.x Catalysts for Low-Temperature CO Oxidation`, Gardner et al., 129, (1991), pp. 114-120.
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Successful Design of Catalysts, `Fine Structure of Novel Gold Catalysts Prepared by Coprecipitation`, edited by T. Inui, published by Elsevier Science Publishers B.V., Amsterdam (1988) pp. 33-42.

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