Compositions – Preservative agents – Anti-oxidants or chemical change inhibitants
Patent
1976-08-27
1977-12-13
Shine, W. J.
Compositions
Preservative agents
Anti-oxidants or chemical change inhibitants
4232132, B01J 2310
Patent
active
040628108
ABSTRACT:
The invention provides a carrier-supported catalyst, wherein alumina partially converted to .alpha.-Al.sub.2 O.sub.3 is the carrier having between 0.2 and 10 weight % of cerium in oxide form deposited thereon as the catalytically active ingredient.
The carrier supported catalyst is made by compressing hydrous alumina or unstable anhydrous alumina into shapes. The shapes are annealed for 10-20 hours at 1000.degree.-1250.degree. C. The annealed shapes are impregnated with an aqueous solution of a cerium salt of a readily decomposable acid and dried at 130.degree.-150.degree. C. The dry cerium salt is decomposed by gradually heating the shapes at 20.degree.-300.degree. C and 450.degree.-550.degree. C, respectively, and the resulting cerium oxide-containing shapes are annealed at 700.degree.-900.degree. C.
REFERENCES:
patent: 3322491 (1967-05-01), Barrett et al.
patent: 3407030 (1968-10-01), Clifford et al.
patent: 3865923 (1975-02-01), Stephens
patent: 3885019 (1975-05-01), Matsushita et al.
Dyrschka Helmut
Glaser Hermann
Vogt Wilhelm
Hoechst Aktiengesellschaft
Shine W. J.
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