Stock material or miscellaneous articles – Hollow or container type article – Polymer or resin containing
Reexamination Certificate
1999-09-27
2003-06-10
Kiliman, Leszek (Department: 1773)
Stock material or miscellaneous articles
Hollow or container type article
Polymer or resin containing
C428S036700, C428S474400, C428S475800, C428S476100, C428S476300, C428S476900, C428S522000
Reexamination Certificate
active
06576308
ABSTRACT:
BACKGROUND OF INVENTION
This invention concerns release sheets (films) useful in sheet molding compound applications, (SMC) thick (or “Takeda”) molding compound (TMC) applications, or in bulk (or “dough”) molding (BMC) applications. This invention also concerns sheet molding compounds made using the release sheets of this invention.
In various processes for producing sheet molding compounds, the process typically includes casting a layer of heat-curable thermosetting resin composition such as an unsaturated polyester composition containing styrene monomer, usually with chopped fiberglass and filler, onto a polymeric film as a release sheet and carrier sheet. Polymeric film is then also applied to the top surface of the heat-curable thermosetting resin composition to form a sandwich composition. The process includes passing the sandwich composition through a plurality of compaction rolls, and then winding the sandwich composition into a roll for partial curing and for later use, for example, in a compression molding system for pressure molded products. The polymeric release and carrier film is typically stripped off and disposed of prior to the compression molding step.
The polymeric carrier film provides a barrier for the particular monomer employed in the thermosetting resin, such as a styrene monomer, yet the film should be easily removable from the sandwich composite so produced. A polyamide polymeric film providing good barrier characteristics for the styrene monomer in the liquid resin is unsuitable for use, since the nylon tends to adhere to the styrene monomer heat-cured thermosetting resin, and is therefore difficult to remove.
A polymeric carrier film having release properties with low crystallinity has been proposed, with the polymeric film comprising a blend of a polyamide, such as nylon 6/66, together with an olefin of defined crystallinity, such as an ethylene vinyl acetate copolymer. Employment of the modified nylon carrier film is described, for example, in European patent application 0 027 191, published Mar. 21, 1984, which is hereby incorporated by reference. Desirable characteristics of such nylon modified support films in the manufacture of sheet molding compounds products has also been described in the publication “Nylon Support Films for the Manufacture of SMC Products,” by P. Stuart Bollen et al, at the 35
th
Annual Technical Conference 1990, Reinforced Plastics Companies Institute, The Society of Plastics Industry, Inc., also hereby incorporated by reference. This publication sets forth the distinct advantages of the modified nylon carrier film with the employment of polyethylene (PE) film to support the formation of the SMC compounds. However, it was reported that PE film, at a low cost and per unit area, relatively inert and with non-adhesive properties, has been exceptionally permeable to the common volatile liquid aromatic hydrocarbons, such as benzene, toluene and styrene monomers, as employed in the heat-curable thermostatic styrene modified resins.
In addition, it may be appreciated that monomer components such as styrene are frequently employed in the resins as crosslinking agents. Undue loss of styrene may lead to useless batch of compound. Previously, the edges of the SMC and TMC have been styrene deprived because styrene could escape through the unsealed film, at the edges of the compound during the process and during maturation, after removal from the maturation area, and prior to molding. Trimming of styrene deprived edges can be a costly loss of compound to the end user.
It should be further noted that while it was possible previously to seal the edges of the film, the force required to pull the film apart was too great to do so without cutting of the film. Molders thus found that separation of the film from the SMC or TMC was inefficient and too expensive since special equipment was required. A need therefore exists for a film which can be sealed at the edges and then peeled apart so that molding compound can be used.
It is therefore desirable to provide for a new and improved, low cost and efficient carrier support film product for the manufacture of SMC, TMC, and BMC products in the processes for production thereof.
SUMMARY OF INVENTION
The present invention provides a solution to one or more of the disadvantages and deficiencies described above. Generally, this invention concerns a carrier release sheet (film), a method of preparation for the sheet, and the system and use of the sheet in sheet molding systems. The release sheet may also be used for TMC and BMC.
In one broad respect, this invention is a multilayer film useful as a release sheet for sheet molding compounds, comprising: (a) a first skin layer; (b) a second skin layer; (c) a barrier layer for monomeric resins wherein the barrier layer is between the first and second skin layers; and wherein the first and second skin layers comprise a mixture of polyolefin and adhesive resin.
In a second broad respect, this invention is a composite useful in molding compound applications, comprising: first and second multilayer release sheets, and a heat-curable resin layer between the first and second multilayer release sheets, wherein the first and second multilayer release sheets, comprise: (a) a first skin layer; (b) a second skin layer; (c) a barrier layer for the heat-curable resin wherein the barrier layer is between the first and second skin layers; and wherein the first and second skin layers comprise a mixture of polyolefin and adhesive resin.
In a third broad respect, this invention is a process for the manufacture of a carrier film, comprising: co-extruding a three layer film, wherein the layers comprise a first skin layer, a second skin layer, and a barrier layer for monomeric resins wherein the barrier layer is between the first and second layers, and wherein the first and second skin layers comprise a mixture of polyolefin and adhesive resin.
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“Compounding,” by Irv J. Leichtle, 45thAnnual Conference, Composites Institute,The Society of Plastics Industry, Inc., Feb. 12-15, 1990, pp. 2-B/1-2-B/6.
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Denehy Daniel G.
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Kiliman Leszek
Pliant Corporation
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