Carboxy-substituted organosilicon stabilizers for a silicate-con

Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing

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252 75, 252 783, 528 25, 556415, 556416, 556418, 556419, 556420, 556423, 556437, C07F 710, C07F 718, C07F 708

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active

048229016

ABSTRACT:
Novel substituted organosilicon carboxylates characterized by the following formula: ##STR1## wherein M is a monovalent cation: Z represents a moiety hydrolyzable to silanol; R.sup.1 represents hydrogen, a monovalent hydrocarbon radical such as methyl, ethyl, phenyl, and the like or a substituted monovalent hydrocarbon radical; a has a value from 0 to 20, b has a value of 1 or 2, c has a value of 0 or 1, n has a value of 2, 3, or 4 and m has a value of from 3 to 15 when a is other than 0 and from about 7 to about 15 when a is 0, are disclosed as useful to provide a silicate-containing antifreeze having enhanced dilute aqueous stability, as are precursors which are convertible to such carboxylates upon addition to base and water, such precursors having the formula: ##STR2## wherein Y is a member selected from the group consisting of ##STR3## the other constituents and values being as described in conjunction with the organosilicon carboxylates; also disclosed are copolymers formed by reacting such carboxylates with an organic or inorganic silicate.

REFERENCES:
patent: 3143524 (1964-08-01), Cooper et al.
patent: 3198820 (1965-08-01), Pines et al.
patent: 3793360 (1974-02-01), Prokai et al.
Chem. Abstracts, vol. 93, No. 192 556a, "Chemical Modification of Silica Gel by Long-Chain Organic Compounds," Vestn. Mosk, Univ., Ser. 2: Khim. 1980, 21(4), 370-3, Staroverov et al.

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